New zinc battery competes with lithium-ion

Enlarge / Lithium-ion batteries do a lot of great things, but they also do this more often than we’d like. (credit: Crushader) Lithium batteries are currently the belle of the battery ball. They have a lot going for them, including high energy storage for their weight and the ability to charge and recharge many times before losing much capacity. But we’re all familiar with the drawbacks, too. Lithium-ion batteries pose a fire risk, and the lithium and cobalt used in them aren’t the most abundant elements, which makes things more expensive. Plenty of other possible battery chemistries could compete with lithium, but getting them to live up to their theoretical potential is difficult. Zinc, for example, performs admirably in your non-rechargeable alkaline batteries, and it could theoretically make a safer and cheaper rechargeable one—with a water-based electrolyte rather than a flammable organic one. This hasn’t happened, though, and the reason becomes apparent if you throw the batteries under a microscope. Read 14 remaining paragraphs | Comments

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New zinc battery competes with lithium-ion

Solid electrolyte may end the catastrophic failures of lithium batteries

Batteries like this one with liquid electrolytes may eventually get a run for their money. pinkyracer Lithium batteries have become a very popular technology, powering everything from cell phones to cars. But that doesn’t mean the technology is without its problems; lithium batteries have been implicated in some critical technological snafus, from exploding laptops to grounded airplanes . Most of these problems can be traced back to the electrolyte, a liquid that helps ions carry charges within the battery. Liquid electrolytes can leak, burn, and distort the internal structure of the battery, swelling it in ways that can lead to a catastrophic failure. The solution, of course, would be to get rid of the liquids. But ions don’t tend to move as easily through solids, which creates another set of problems. Now, researchers have formulated a solid in which lithium ions can move about five times faster than any previously described substance. Better yet, the solid—a close chemical relative of styrofoam—helps provide structural stability to the battery. Don’t expect to see a styrofoam battery in your next cellphone though, as the material needs to be heated to 60°C in order to work. The problem with liquid electrolytes has to do with the fact that, during recharging, lithium ions end up forming deposits of metal inside the battery. These create risks of short circuits (the problem that grounded Boeing’s Dreamliner 787) and can damage the battery’s structure, causing leaks and a fire risk. Solid electrodes get around this because the lithium ions will only come out of the electrolyte at specific locations within the solid, and can’t form the large metal deposits that cause all of the problems. Read 6 remaining paragraphs | Comments

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Solid electrolyte may end the catastrophic failures of lithium batteries